Carbon Dioxide Sequestration Technologies

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    Carbon sequestration is the process of capture and long-term storage of atmospheric carbon dioxide(CO2) and may refer specifically to:
    1. “The process of removing carbon from the atmosphere and depositing it in a reservoir.” Then carried out deliberately, this may also be referred to as carbon dioxide removal, which is a form of geoengineering.
    2. The process of carbon capture and storage, where carbon dioxide is removed from flue gases such as on power stations, before being stored in underground reservoirs.
    3. Natural biogeochemical cycling of carbon between the atmosphere and reservoirs, such as by chemical weathering of rocks.
    INTRODUCTION
    Carbon sequestration describes long-term storage of carbon dioxide or other forms of carbon to mitigate the global warming potential of increasing the atmospheric content of carbon dioxide. It has been proposed as a way to slow the atmospheric and marine accumulation of greenhouse gases, which are released by burning fossil fuels. Carbon dioxide is naturally captured from the atmosphere through biological, chemical or physical processes. Some anthropogenic sequestration techniques exploit these natural processes, while some use entirely artificial processes.Carbon dioxide may be captured as a pure by-product in processes related to petroleum refining or from flue gases from power generation. CO2 sequestration includes the storage part of carbon capture and storage, which refers to large-scale, permanent artificial capture and sequestration of industrially produced CO2 using subsurface saline aquifers, reservoirs, ocean water, aging oil fields, or other carbon sinks.

    PART ONE: BIOSEQUESTRATION
    Carbon sequestration through biological processes affects the global carbon cycle. Examples include major climatic fluctuations, such as the Azolla event, which created the current Arctic climate. Such processes created fossil fuels, as well as clathrate and limestone. By manipulating such processes, geoengineers seek to enhance sequestration.

    • Peat Production: Peat bogs are a very important carbon store. By creating new bogs, or enhancing existing ones, carbon can be sequestered.
    • Reforestation: Reforestation is the replanting of trees on marginal crop and pasture lands to incorporate carbon from atmospheric CO2 into biomass. For this process to succeed the carbon must not return to the atmosphere from burning or rotting when the trees die. To this end, the trees must grow in perpetuity or the wood from them must itself be sequestered, e.g., via biochar, bio-energy with carbon storage (BECS or landfill. Short of growth in perpetuity, however, reforestation with long-lived trees (>100 years) will sequester carbon for a more graduated release, minimizing impact during the “carbon crisis” of the 21st century.
    • Wetland Restoration: Wetland soil is an important carbon sink; 14.5% of the world’s soil carbon is found in wetlands, while only 6% of the world’s land is composed of wetlands.

    Agriculture
    Globally, soils are estimated to contain approximately 1,500 gigatons of organic carbon to 1 m depth, more than the amount in vegetation and the atmosphere.
    Modification of agricultural practices is a recognized method of carbon sequestration as soil can act as an effective carbon sink offsetting as much as 20% of 2010 carbon dioxide emissions annually. (See No-till)
    Carbon emission reduction methods in agriculture can be grouped into two categories: reducing and/or displacing emissions and enhancing carbon removal. Some of these reductions involve increasing the efficiency of farm operations (i.e. more fuel-efficient equipment) while some involve interruptions in the natural carbon cycle. Also, some effective techniques (such as the elimination of stubble burning) can negatively impact other environmental concerns (increased herbicide use to control weeds not destroyed by burning).
    Reducing emissions
    Increasing yields and efficiency generally reduces emissions as well, since more food results from the same or less effort. Techniques include more accurate use of fertilizers, less soil disturbance, better irrigation, and crop strains bred for locally beneficial traits and increased yields.
    Replacing more energy intensive farming operations can also reduce emissions. Reduced or no-till farming requires less machine use and burns correspondingly less fuel per acre. However, no-till usually increases use of weed-control chemicals and the residue now left on the soil surface is more likely to release its CO2 to the atmosphere as it decays, reducing the net carbon reduction.
    In practice, most farming operations that incorporate post-harvest crop residues, wastes and byproducts back into the soil provide a carbon storage benefit. This is particularly the case for practices such as field burning of stubble – rather than releasing almost all of the stored CO
    2 to the atmosphere, tillage incorporates the biomass back into the soil where it can be absorbed and a portion of it stored permanently.
    Enhancing carbon removal
    All crops absorb CO2 during growth and release it after harvest. The goal of agricultural carbon removal is to use the crop and its relation to the carbon cycle to permanently sequester carbon within the soil. This is done by selecting farming methods that return biomass to the soil and enhance the conditions in which the carbon within the plants will be reduced to its elemental nature and stored in a stable state. Methods for accomplishing this include:
    Use cover crops such as grasses and weeds as temporary cover between planting seasons
    Concentrate livestock in small paddocks for days at a time so they graze lightly but evenly. This encourages roots to grow deeper into the soil. Stock also till the soil with their hooves, grinding old grass and manures into the soil.
    Cover bare paddocks with hay or dead vegetation. This protects soil from the sun and allows the soil to hold more water and be more attractive to carbon-capturing microbes.
    Restore degraded land, which slows carbon release while returning the land to agriculture or other use.
    Agricultural sequestration practices may have positive effects on soil, air, and water quality, be beneficial to wildlife, and expand food production. On degraded croplands, an increase of 1 ton of soil carbon pool may increase crop yield by 20 to 40 kilograms per hectare of wheat, 10 to 20 kg/ ha for maize, and 0.5 to 1 kg/ha for cowpeas.
    The effects of soil sequestration can be reversed. If the soil is disrupted or tillage practices are abandoned, the soil becomes a net source of greenhouse gases. Typically after 15 to 30 years of sequestration, soil becomes saturated and ceases to absorb carbon. This implies that there is a global limit to the amount of carbon that soil can hold.
    Many factors affect the costs of carbon sequestration including soil quality, transaction costs and various externalities such as leakage and unforeseen environmental damage. Because reduction of atmosperic CO2 is a long-term concern, farmers can be reluctant to adopt more expensive agricultural techniques when there is not a clear crop, soil, or economic benefit. Governments such as Australia and New Zealand are considering allowing farmers to sell carbon credits once they document that they have sufficiently increased soil carbon content.
    Ocean-related Iron fertilization
    Ocean iron fertilization is an example of such a geoengineering technique. Iron fertilization attempts to encourage phytoplankton growth, which removes carbon from the atmosphere for at least a period of time. This technique is controversial due to limited understanding its complete effects on the marine ecosystem,including side effects and possibly large deviations from expected behavior. Such effects potentially include release of nitrogen oxides, and disruption of the ocean’s nutrient balance.
    Natural iron fertilisation events (e.g., deposition of iron-rich dust into ocean waters) can enhance carbon sequestration. Sperm whales act as agents of iron fertilisation when they transport iron from the deep ocean to the surface during prey consumption and defecation. Sperm whales have been shown to increase the levels of primary production and carbon export to the deep ocean by depositing iron rich feces into surface waters of the Southern Ocean. The iron rich feces causes phytoplankton to grow and take up more carbon from the atmosphere. When the phytoplankton dies, some of it sinks to the deep ocean and takes the atmospheric carbon with it. By reducing the abundance of sperm whales in the Southern Ocean, whaling has resulted in an extra 2 million tonnes of carbon remaining in the atmosphere each year.
    Urea fertilisation
    Main article: Ocean nourishment
    Ian Jones proposes fertilizing the ocean with urea, a nitrogen rich substance, to encourage phytoplankton growth.[citation needed]
    Australian company Ocean Nourishment Corporation (ONC) plans to sink hundreds of tonnes of urea into the ocean to boost CO2-absorbing phytoplankton growth as a way to combat climate change. In 2007, Sydney-based ONC completed an experiment involving 1 tonne of nitrogen in the Sulu Sea off the Philippines.[25]
    Mixing layers
    Encouraging various ocean layers to mix can move nutrients and dissolved gases around, offering avenues for geoengineering.[26] Mixing may be achieved by placing large vertical pipes in the oceans to pump nutrient rich water to the surface, triggering blooms of algae, which store carbon when they grow and export carbon when they die.[26][27][28] This produces results somewhat similar to iron fertilization. One side-effect is a short-term rise in CO
    2, which limits its attractiveness.[29]
    Physical processes
    Biochar can be landfilled, used as a soil improver or burned using carbon capture and storage
    Biomass-related
    Bio-energy with carbon capture and storage (BECCS)
    Main article: Bio-energy with carbon capture and storage
    BECCS refers to biomass in power stations and boilers that use carbon capture and storage.The carbon sequestered by the biomass would be captured and stored, thus removing carbon dioxide from the atmosphere.
    This technology is sometimes referred to as bio-energy with carbon storage, BECS, though this term can also refer to the carbon sequestration potential in other technologies, such as biochar
    Burial
    Burying biomass (such as trees) directly, mimics the natural processes that created fossil fuels. Landfills also represent a physical method of sequestration.
    Biochar burial
    Biochar is charcoal created by pyrolysis of biomass waste. The resulting material is added to a landfill or used as a soil improver to create terra preta. Biogenic carbon is recycled naturally in the carbon cycle. Pyrolysing it to biochar renders the carbon relatively inert so that it remains sequestered in soil. Further, the soil encourages bulking with new organic matter, which gives additional sequestration benefit. In the soil, the carbon is unavailable for oxidation to CO2 and consequential atmospheric release. The mechanisms related to biochar are referred to as bio-energy with carbon storage, BECS.
    Ocean storage
    River mouths bring large quantities of nutrients and dead material from upriver into the ocean as part of the process that eventually produces fossil fuels. Transporting material such as crop waste out to sea and allowing it to sink exploits this idea to increase carbon storage. International regulations on marine dumping may restrict or prevent use of this technique.
    Subterranean injection
    Main article: Carbon capture and storage
    Carbon dioxide can be injected into depleted oil and gas reservoirs and other geological features, or can be injected into the deep ocean.
    The first large-scale CO2 sequestration project which began in 1996 is called Sleipner, and is located in the North Sea where Norway’s StatoilHydro strips carbon dioxide from natural gas with amine solvents and disposed of this carbon dioxide in a deep saline aquifer. In 2000, a coal-fueled synthetic natural gas plant in Beulah, North Dakota, became the world’s first coal-using plant to capture and store carbon dioxide, at the Weyburn-Midale Carbon Dioxide Project.
    CO2 has been used extensively in enhanced crude oil recovery operations in the United States beginning in 1972. There are in excess of 10,000 wells that inject CO2 in the state of Texas alone. The gas comes in part from anthropogenic sources, but is principally from large naturally occurring geologic formations of CO2. It is transported to the oil-producing fields through a large network of over 5,000 kilometres (3,100 mi) of CO2 pipelines. The use of CO2 for enhanced oil recovery (EOR) methods in heavy oil reservoirs in the Western Canadian Sedimentary Basin (WCSB) has also been proposed. However, transport cost remains an important hurdle. An extensive CO2 pipeline system does not yet exist in the WCSB. Athabasca oil sands mining that produces CO2 is hundreds of kilometers north of the subsurface Heavy crude oil reservoirs that could most benefit from CO2 injection.
    Chemical processes
    Carbon, in the form of CO2 can be removed from the atmosphere by chemical processes, and stored in stable carbonate mineral forms. This process is known as ‘carbon sequestration by mineral carbonation’ or mineral sequestration. The process involves reacting carbon dioxide with abundantly available metal oxides–either magnesium oxide (MgO) or calcium oxide (CaO)–to form stable carbonates. These reactions are exothermic and occur naturally (e.g., the weathering of rock over geologic time periods).
    CaO + CO2 → CaCO3MgO + CO2 → MgCO3
    Calcium and magnesium are found in nature typically as calcium and magnesium silicates (such as forsterite and serpentinite) and not as binary oxides. For forsterite and serpentine the reactions are:
    Mg2SiO4 + 2CO2 = 2MgCO3 + SiO2
    Mg3Si2O5(OH)4+ 3CO2 = 3MgCO3 + 2SiO2 + 2H2O
    The following table lists principal metal oxides of Earth’s crust. Theoretically up to 22% of this mineral mass is able to form carbonates.
    These reactions are slightly more favorable at low temperatures. This process occurs naturally over geologic time frames and is responsible for much of the Earth’s surface limestone. The reaction rate can be made faster, for example by reacting at higher temperatures and/or pressures, or by pre-treatment, although this method requires additional energy.
    CO
    2 naturally reacts with peridotite rock in surface exposures of ophiolites, notably in Oman. It has been suggested that this process can be enhanced to carry out natural mineralisation of CO2.
    Industrial use
    Traditional cement manufacture releases large amounts of carbon dioxide, but newly developed cement types from Novacem can absorb CO2 from ambient air during hardening. A similar technique was pioneered by TecEco, which has been producing “EcoCement” since 2002.
    In Estonia, oil shale ash, generated by power stations could be used as sorbents for CO2 mineral sequestration. The amount of CO2 captured averaged 60–65% of the carbonaceous CO2 and 10–11% of the total CO2 emissions.